Okay, I like Brooke. She has substance and I think she's a great character. But that having been said, she is not the one for Lucas.
For starters, Lucas has always been in love with Peyton. Every year his predictions were about her and he used to always say she deserved better than Nathan.
Also, even when Lucas was dating Brooke, he always had a thing for Peyton. That's pretty clear because how many ever times Brooke told him to stay away from her, he couldn't. If he really loved Brooke then he would have been able to let go of Peyton.
And yeah, Peyton screwed up the first time when she kissed...
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