Alright Avatar fans lets see who is the best bender.(Avatar state does not count because it is the concentration of all past avatars and thier skills as a bender)
Personally I believe it is zuko becouse of the redirecting lightning. Iroh may have taught it but he perfected it. Iroh never used it enough to be said that he mastered it but zuko was and he redirected a large amount from Azula with only a second to prepare and survived.
It's obviously Azula. Not only has she mastered Fire and Lightning bending, but she has skills in weaponry and acrobatics as showed in 'The Day of Black Sun Part 2: The Eclipse'. She beat Aang and Toph and Sokka with no bending at all! As for the re-directing lightning, I'm sure if Azula was taught it, she'd master it easily, as she dose with anything.
toph...I mean come on...she metal bends...thats never been done before, she pretty much created a new type of bending, well I guess technically metal is earth but still pretty amazing.
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Azula is a Fire Bending Prodigy.