Bond movies are a guilty pleasure of mine. I love how each one has it's own theme song and this particularly one has the best theme song ever! I mean...it's Paul McCartney!
Video by vmarcenne. Music by Clint Mansell. An example of how music can define a movie. The jittery, chaotic atmosphere of the film is perfectly facilitated by it's soundtrack.
So this isn't on the official soundtrack but it's an awesome version of this song. It was performed and recorded specifically for the show by some CW execs.