Fire ants often attack small animals and can kill them.
Unlike many other ants, which bite and then spray acid on the wound, fire ants only bite to get a grip and then sting (from the abdomen) and inject a toxic alkaloid venom (piperidine).
For humans, this is a painful sting, which leaves a sensation similar to what one feels when they get burned by fire - hence the name fire ant - and the aftereffects of the sting can be deadly to sensitive individuals.