Besides Episodes I through VI there is...
1. The new (and totally awesome) Clone Wars animated movie and TV series:
Film:
link
TV Show:
link)
2. The vast collection of novels:
link
3. The equally vast array of comics:
link
4. The huge list of Star Wars games, many of which contain new storylines:
link
5. The online comic, partner to the new TV show:
link
6. The old Clone Wars animated show:
link
7. Ewoks: The Battle for Endor, a 1985 made-for-TV film:
link
8. Star Wars: Droids—The Adventures of R2-D2 and C-3PO, an animated television series:
link
9. The Star Wars Holiday Special. The worst Star Wars piece ever made. There is an Urban Legend that at a sci-fi convention in Australia, George Lucas once said "If I had the time and a hammer, I would smash every copy of the Holiday Special."
But it does exist:
link
10. A huge mountain of Fan Fiction. some good, some bad:
link
I have done some myself using Hasbro's toy line, links to which are at:
link
11. The still in the works live action TV show set between Revenge of the Sith and A New Hope:
link
Did I miss anything?