1. Captain Hook and Ringmaster: Captain Hook would be cast as The Ringmaster because of their black mustaches. Okay maybe The Ringmaster from Dumbo would of have been a better fit.
2. Dr. Facilier and Dr. Doom: Dr. Facilier would be cast as Dr. Doom, because they're evil doctors who hire various villains to help him in his plan.
3. Kim Possible and Black Widow: Kim Possible would be Black Widow because she would be the gadget handy type much like Black Widow.
4. Shego and Mystique: Shego would be Mystique because she would be an evil equivalent to Kim Possible much like how Mystique is an evil...
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